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AP Chemistry - 50 Key Concepts

Prepare for AP Chemistry with 50 flashcards covering atomic structure, bonding, thermodynamics, kinetics, and more.

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Front

What is the difference between the atomic number and the mass number?

Back

Atomic number is the number of protons; mass number is protons plus neutrons. Atomic number defines the element's identity on the periodic table.

Front

Define isotopes.

Back

Atoms of the same element with the same number of protons but different numbers of neutrons. Example: Carbon-12 and Carbon-14.

Front

What does the Aufbau Principle state?

Back

Electrons fill the lowest energy orbitals first. Follows the order: 1s, 2s, 2p, 3s, etc.

Front

What is the Pauli Exclusion Principle?

Back

An orbital can hold a maximum of two electrons with opposite spins. No two electrons in an atom can have the same four quantum numbers.

Front

What is Hund's Rule?

Back

Electrons fill degenerate orbitals singly before pairing up. This minimizes electron-electron repulsion within a subshell.

Front

What is the equation for the energy of a photon?

Back

E = hν or E = hc/λ h is Planck's constant (6.626 x 10^-34 J·s).

Front

What is the periodic trend for electronegativity?

Back

Increases across a period (left to right) and decreases down a group. Fluorine is the most electronegative element.

Front

What is the periodic trend for atomic radius?

Back

Decreases across a period and increases down a group. Decreases across a period due to increased effective nuclear charge (Zeff).

Front

What is the primary difference between ionic and covalent bonding?

Back

Ionic involves electron transfer; covalent involves electron sharing. Ionic bonds typically form between metals and non-metals.

Front

Define Lattice Energy.

Back

The energy required to separate one mole of an ionic solid into gaseous ions. Higher charges and smaller radii result in higher lattice energy.

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